The text emphasizes the methodologies and strategies for finding maintainability, sustainability, dependability, and reliability. It discusses how Industry 5.0 affects networks and gives ideas about diversification and an interdisciplinary approach in the field of network reliability. Features: Covers different methods for enhancing the network's Reliability, maintainability, and performance based on applications of the universal generating function, Lz-transform, and Monte Carlo simulation Methodology. Discusses the concepts of Network reliability in Industry 5.0, in which we can enhance the Maintainability, Sustainability, Reliability, and dependability of the different complex networks and systems. Provides a comparative framework for the network reliability used in real life for future work. Explains how Industry 5.0 affects networks and gives ideas about diversification and an interdisciplinary approach in the field of Network reliability. Highlights future research and problems in network reliability and focus on how emerging networks are used in the agriculture field, the food supply chain network, and multistage interconnection networks. The text is primarily written for graduate students and academic researchers in industrial engineering, systems engineering, production engineering, reliability engineering, mechanical engineering, and mathematics.